Issue 17, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Effect of substituents on the stereoselectivity of the acid-catalysed hydrolysis of a series of aryloxirans. A new application of the Hammett equation

Carlo Battistini,   Aldo Balsamo,   Giancarlo Berti,   Paolo Crotti,   Bruno Macchia  and  Franco Macchia  

Abstract

Correlation of the logarithms of the ratios of cis to trans diols formed in the acid-catalysed hydrolysis of 13 1-arylcyclohexene oxides with the σ+ constants indicates that there is a higher degree of carbocationic character in the transition state leading to the cis-product.

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Article information

DOI
https://doi.org/10.1039/C39740000712
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 712-713

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Effect of substituents on the stereoselectivity of the acid-catalysed hydrolysis of a series of aryloxirans. A new application of the Hammett equation

C. Battistini, A. Balsamo, G. Berti, P. Crotti, B. Macchia and F. Macchia, J. Chem. Soc., Chem. Commun., 1974, 712 DOI: 10.1039/C39740000712

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