13 C N.m.r. spectra of nitronate anions show a marked solvent-dependent shift which correlates with electronic distribution in these anions; a deshielding effect of the nitronate grouping observed with 1H n.m.r. spectra shows the axial conformer of 2-substituted cyclo-hexanenitronate anions to be preferred.
A. L. Begbie, W. R. Bowman, B. T. Golding and W. P. Watson, J. Chem. Soc., Chem. Commun., 1974, 645 DOI: 10.1039/C39740000645
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