Enantioselective cyclopropanation (70% enantiomeric excess) through carbenoid reaction of diazoalkanes has been achieved using bis-[(+)-camphorquinonedioximato]cobalt(II) as catalyst.
Y. Tatsuno, A. Konishi, A. Nakamura and S. Otsuka, J. Chem. Soc., Chem. Commun., 1974, 588 DOI: 10.1039/C39740000588
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