Addition of a particular radical to ethylene is ca. 11 kcal mol–1 more exothermic than the corresponding addition to benzene to give a cyclohexadienyl radical; use of this difference enables a common pattern of reactivity for the two reactions to be established.
R. A. Jackson, J. Chem. Soc., Chem. Commun., 1974, 573 DOI: 10.1039/C39740000573
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