Issue 14, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation of closo- and nido-metallocarboranes from closo-C2B9 and -C2B7 carborbranes; molecular structures of closo-1,1-(Me2PhP)2-2,4-Me2-1,2,4-PtC2B9H9 and nido-10,10-(Et3P)2-2,8-Me2-10,2,8-PtC2B7H7

Michael Green,   John L. Spencer,   F. Gordon A. Stone  and  Alan J. Welch  

Abstract

Reaction of closo-1,6-Me2-1,6-C2B7H7 with [Pt(Et3P)3] affords nido-10,10-(Et3P)2-2,8-Me2-10,2,8-PtC2B7H7, a stereochemically non-rigid molecule; the structural identity of closo-1,1-(Me2PhP)2-2,4-Me2-1,2,4-PtC2B9H9 and the nido-metallocarborane are established by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39740000571
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 571-572

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Formation of closo- and nido-metallocarboranes from closo-C2B9 and -C2B7 carborbranes; molecular structures of closo-1,1-(Me2PhP)2-2,4-Me2-1,2,4-PtC2B9H9 and nido-10,10-(Et3P)2-2,8-Me2-10,2,8-PtC2B7H7

M. Green, J. L. Spencer, F. G. A. Stone and A. J. Welch, J. Chem. Soc., Chem. Commun., 1974, 571 DOI: 10.1039/C39740000571

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