Interaction of sodium borohydride with salts of cobalt(II) or nicel(II) produces metal borides that have been found to contain hydrogen; stoicheiometries Co2B and Ni2B as have been suggested previously are inadequate in explaining the physical and chemical properties of these substances, and the formulations (Co2B)5·H3 and (Ni2B)2·H3 have been tentatively assigned.
P. C. Maybury, R. W. Mitchell and M. F. Hawthorne, J. Chem. Soc., Chem. Commun., 1974, 534 DOI: 10.1039/C39740000534
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