SCHEDULED MAINTENANCE
Pyrolysis of 9-tellurabicyclo[3,3,1]nona-2,6-diene (II) in [2H8]toluene at 175° leads to loss of elemental tellurium and quantitative formation of bicyclo-[5,1,0]octa-2,5-diene (III) which was also formed independently by the action of Te2– anion on the dibromide (I) during the preparation of (II).
E. Cuthbertson and D. D. MacNicol, J. Chem. Soc., Chem. Commun., 1974, 498 DOI: 10.1039/C39740000498
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