Issue 12, 1974

The cyclohexane-1,4-diyl mechanism for Cope rearrangements. Phenyl substitution in the oxy-Cope system

Abstract

Phenyl substituted oxy-Cope systems give rate ratios for the two competing components which rule out the intermediacy of cyclohexane-1,4-diyl diradicals in these rearrangements, although such intermediates have recently been implicated in the rearrangements of some phenyl hexa-1,5-dienes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 491-492

The cyclohexane-1,4-diyl mechanism for Cope rearrangements. Phenyl substitution in the oxy-Cope system

A. Viola, A. J. Padilla, D. M. Lennox, A. Hecht and R. J. Proverb, J. Chem. Soc., Chem. Commun., 1974, 491 DOI: 10.1039/C39740000491

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