(Monohydrogen meso-tetraphenylporphyrinato)-tricarbonylrhenium(I) has been prepared; its 1H n.m.r. spectrum in CDCl3 can be interpreted in terms of co-ordination of the rhenium atom by three adjacent pyrrole nitrogen atoms of the porphyrin, with the hydrogen atom bonded to the fourth nitrogen atom of unco-ordinated pyrrole.
T. S. Srivastava, C. Hrung and M. Tsutsui, J. Chem. Soc., Chem. Commun., 1974, 447 DOI: 10.1039/C39740000447
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