Certain cationic square-planar IrI and RhI complexes with chelating tertiary diphosphine ligands, [M(L–L)2]+, exhibit photoluminescence in the solid state at 25°, while their adducts with O2, CO, and H2 do not; emission and absorption spectra for a number of emitting compounds are compared, and some practical uses of the phenomena are suggested.
R. Brady, W. V. Miller and L. Vaska, J. Chem. Soc., Chem. Commun., 1974, 393 DOI: 10.1039/C39740000393
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