The macrocyclic polyethers, (7) and (8), have been synthesised stereospecifically from the diastereoisomeric acyclic methylene acetals, (1) and (2), obtained from (±)-cyclohexane-trans-1,2-diol; both (7) and (8) form stable complexes with metal cations.
J. F. Stoddart and C. M. Wheatley, J. Chem. Soc., Chem. Commun., 1974, 390 DOI: 10.1039/C39740000390
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