The copper complex of a polyoxime, {[CH2]1·6[C(![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
NOH)C(NOH)]0·8[C(O)]0·2} catalyzes the ‘Michael’type addition reaction of acrolein and an alcohol yielding exclusively β-alkoxypropionaldehyde, polymerizes acrylonitrile under H2 at 40–90 atm and reversibly takes up molecular oxygen and carbon monoxide even in methanol or water after being treated with hydrazine hydrate.
S. J. Kim and T. Takizawa, J. Chem. Soc., Chem. Commun., 1974, 356 DOI: 10.1039/C39740000356
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