Issue 9, 1974

Relationship between the photoelectron spectra and torsional barriers of aminophosphines

Abstract

The trends in the nitrogen and phosphorus lone-pair ionization potentials of Me2NP(CF3)2(1), Me2NP(Cl)CF3, (2), and Me2NPCl2(3) suggest that the P–N torsional barriers in aminophosphines arise predominantly from steric and lone pair–lone pair repulsion effects.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 340-341

Relationship between the photoelectron spectra and torsional barriers of aminophosphines

A. H. Cowley, M. J. S. Dewar, J. W. Gilje, D. W. Goodman and J. R. Schweiger, J. Chem. Soc., Chem. Commun., 1974, 340 DOI: 10.1039/C39740000340

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