Issue 9, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Relationship between the photoelectron spectra and torsional barriers of aminophosphines

Alan H. Cowley,   Michael J. S. Dewar,   John W. Gilje,   D. Wayne Goodman  and  Jerald R. Schweiger  

Abstract

The trends in the nitrogen and phosphorus lone-pair ionization potentials of Me2NP(CF3)2(1), Me2NP(Cl)CF3, (2), and Me2NPCl2(3) suggest that the P–N torsional barriers in aminophosphines arise predominantly from steric and lone pair–lone pair repulsion effects.

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Article information

DOI
https://doi.org/10.1039/C39740000340
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 340-341

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Relationship between the photoelectron spectra and torsional barriers of aminophosphines

A. H. Cowley, M. J. S. Dewar, J. W. Gilje, D. W. Goodman and J. R. Schweiger, J. Chem. Soc., Chem. Commun., 1974, 340 DOI: 10.1039/C39740000340

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