New carbido-carbonyl cluster compounds of rhodium have been isolated and two of them, characterized by crystallographic methods, have been formulated as Rh8(CO)19C and [H3O][Rh15(CO)28C2]; the synthesis of carbido-carbonyl clusters has been extended to cobalt for which the anion [Co6(CO)15C]2– has been obtained.
V. G. Albano, P. Chini, S. Martinengo, M. Sansoni and D. Strumolo, J. Chem. Soc., Chem. Commun., 1974, 299 DOI: 10.1039/C39740000299
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