The X-ray structural analysis of a substituted tricarbonylallyliron cationic intermediate unambiguously demonstrates that tricarbonyl(trans, trans-hexa-2,4-diene)iron undergoes stereospecific endo attack under Friedel-Crafts conditions.
E. O. Greaves, G. R. Knox, P. L. Pauson, S. Toma, G. A. Sim and D. I. Woodhouse, J. Chem. Soc., Chem. Commun., 1974, 257 DOI: 10.1039/C39740000257
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