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Lasiocoryin from Lasiocorys capensis(Labiatae) is the first 9,13-epoxylabdane (grindelane) diterpenoid to have its structure elucidated by crystallographic analysis; it forms a novel cyclic dimeric acetal on treatment with acid, and this study makes a minor correction to, but otherwise confirms, the stereochemistry of lagochilin.
G. Gafner, G. J. Kruger and D. E. A. Rivett, J. Chem. Soc., Chem. Commun., 1974, 249 DOI: 10.1039/C39740000249
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