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Issue 6, 1974
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Use of tritium nuclear magnetic resonance for the direct location of 3H in biosynthetically-labelled penicillic acid

Abstract

In a first application of 3H n.m.r. spectroscopy to a biosynthetic investigation, namely the incorporation of [3H]acetate by Penicillium cyclopium into penicillic acid (I), the stereospecificity of labelling of the vinyl methylene group is directly demonstrated and a biosynthetic pathway thereby proposed.

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Article type: Paper
DOI: 10.1039/C39740000220
J. Chem. Soc., Chem. Commun., 1974, 220-221

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    Use of tritium nuclear magnetic resonance for the direct location of 3H in biosynthetically-labelled penicillic acid

    J. M. A. Al-Rawi, J. A. Elvidge, D. K. Jaiswal, J. R. Jones and R. Thomas, J. Chem. Soc., Chem. Commun., 1974, 220
    DOI: 10.1039/C39740000220

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