Issue 6, 1974

Low temperature protonation of cyclo-octa-1,5-diene-(duroquinone)nickel(0)

Abstract

Cyclo-octa-1,5-diene(duroquinone)nickel(O) has been shown to protonate at the duroquinone carbonyls in HSO3F to yield a stable dication. The chemical shift of the OH protons indicates very extensive positive charge delocalization through backbonding.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 205-205

Low temperature protonation of cyclo-octa-1,5-diene-(duroquinone)nickel(0)

M. Brookhart and G. J. Young, J. Chem. Soc., Chem. Commun., 1974, 205 DOI: 10.1039/C39740000205

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