Issue 5, 1974

Metallation of azobenzenes by fluorine-abstraction: structure of a ruthenium complex containing nonafluoro(phenylazo)phenyl-2C,N′ and diphenyl-2-(η-cyclopentadienylphenyl)phosphine groups

Abstract

The formation of metallated azobenzene derivatives by fluorine-abstraction reactions using nucleophilic transition metal reagents has been achieved; the structure of an ortho-metallated complex, derived from decafluoroazobenzene and also containing a Ph2P(C6H4C5H4) ligand is described.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 185-186

Metallation of azobenzenes by fluorine-abstraction: structure of a ruthenium complex containing nonafluoro(phenylazo)phenyl-2C,N′ and diphenyl-2-(η-cyclopentadienylphenyl)phosphine groups

M. I. Bruce, R. C. F. Gardner, B. L. Goodall, F. G. A. Stone, R. J. Doedens and J. A. Moreland, J. Chem. Soc., Chem. Commun., 1974, 185 DOI: 10.1039/C39740000185

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