Issue 5, 1974

A new route to nitrenium ions via an electron transfer reaction of aminyl radicals

Abstract

A convenient and mild route to arylnitrenium ions is described involving deoxygenation of aryl nitroxides by trialkyl phosphites in methanol or ethanol, and evidence is presented which suggests that redox transfer between arylaminyl radicals is responsible.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 179-180

A new route to nitrenium ions via an electron transfer reaction of aminyl radicals

J. I. G. Cadogan and A. G. Rowley, J. Chem. Soc., Chem. Commun., 1974, 179 DOI: 10.1039/C39740000179

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