The new complex Rh2[P(OMe)3]8 which has a bicapped trigonal antiprismatic structure at room temperature undergoes a specific equatorial intermolecular ligand exchange at higher temperatures rather than any intramolecular ligand exchange between equatorial and axial sites.
R. Mathieu and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1974, 147 DOI: 10.1039/C39740000147
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