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The high-spin cobalt(II) complex [Co(pfp)2(H2O)2]2–(pfp = perfluoropinacolato dianion) reacts reversibly with oxygen to give the ion [Co(pfp)(Hpfp)O2]–, isolated as a stable tetralkylammonium salt; no oxidation of the cobalt atom appears to have occurred, and it is thought that the oxygen is attached to the metal by π-bonding.
C. J. Willis, J. Chem. Soc., Chem. Commun., 1974, 117 DOI: 10.1039/C39740000117
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