The slope (β) of a Brönsted plot of the microscopic pKa values of the -SH function of a series of ionic species vs. the logarithm of the second-order rate constants for reaction of each species with benzene oxide is 0.22 indicating an early transition state.
D. M. E. Reuben and T. C. Bruice, J. Chem. Soc., Chem. Commun., 1974, 113 DOI: 10.1039/C39740000113
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