SCHEDULED MAINTENANCE
The efficient catalysis by [Co(mnt)2]22–(mnt ![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
maleonitriledithiolate) of the reaction 2PhCH2SH + O2→ PhCH2SSCH2Ph + H2O2 in acetonitrile, acid-buffered with excess of PhMe2N/PhMe2NH+ClO4–, is described; the mechanism involves sequential co-ordinative activation of thiol and oxygen, the reactive intermediate being PhMe2NH––O2–[Co(mnt)2]2–SCH2Ph2–.
I. G. Dance, R. C. Conrad and J. E. Cline, J. Chem. Soc., Chem. Commun., 1974, 13 DOI: 10.1039/C39740000013
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