Evidence for a reversible α-hydrogen abstraction from methyl groups of CoCH3(PPh3)3 and RhCH3(PPh3)3 involving intermediate carbene-hydride formation is presented on the basis of the mass spectrometric analysis of polydeuteriated methanes formed in the reaction of D2 with CoCH3(PPh3)3 and RhCH3(PPh3) in toluene.
L. S. Pu and A. Yamamoto, J. Chem. Soc., Chem. Commun., 1974, 9 DOI: 10.1039/C39740000009
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