Issue 14, 1973
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Antimony halides as solvents. Part X. The Lewis basicity of amines in liquid antimony trichloride

Philip V. Johnson  and  Edward C. Baughan  

Abstract

The Lewis basicity of 12 amines has been measured by electrical conductance for the reaction Am: + 2SbCl3⇄ Am:SbCl2++ SbCl4–(A) in liquid antimony trichloride medium at 75°C. Compared with their pKa's (proton basicity) in water tertiary amines are stronger bases than primary amines towards the SbCl2+ ion. For primary amines the pKa's are linearly related to the equilibrium constants (A). Octadecylamine appears to form micelles.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/P29730001958
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1973, 1958-1960

Permissions

Request permissions

Antimony halides as solvents. Part X. The Lewis basicity of amines in liquid antimony trichloride

P. V. Johnson and E. C. Baughan, J. Chem. Soc., Perkin Trans. 2, 1973, 1958 DOI: 10.1039/P29730001958

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements