Secondary and tertiary carbonium ions with a β-diphenylphosphinyl substituent, generated by solvolysis of sulphonates, or electrophilic attack on suitable olefins, rearrange exclusively by diphenylphosphinyl migration. The preference for this supposedly unfavourable reaction pathway is investigated.
D. Howells and S. Warren, J. Chem. Soc., Perkin Trans. 2, 1973, 1472 DOI: 10.1039/P29730001472
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...