The activation parameters for the pyrolysis of the four S-butyl thioacetates suggest that the mechanism of the reaction is similar to that of the acetates. Evidence is presented showing that there is less charge development in the transition states for the reactions of the sulphur compounds.
D. B. Bigley and R. E. Gabbott, J. Chem. Soc., Perkin Trans. 2, 1973, 1293 DOI: 10.1039/P29730001293
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