Dinitrogen tetroxide is found to nitrate aromatic hydrocarbons cleanly and in high yield. Some of the characteristics of this reaction have been examined and from competitive rate studies, inferences are drawn as to the mechanism of the reaction.
G. R. Underwood, R. S. Silverman and A. Vanderwalde, J. Chem. Soc., Perkin Trans. 2, 1973, 1177 DOI: 10.1039/P29730001177
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