Rates of halogen exchange between potassium iodide and 1-iodo-2,4-dinitrobenzene have been measured in six dipolar aprotic solvents and the results compared with those obtained in methanol. The effect of changing from methanol to a dipolar aprotic solvent is interpreted in terms of an initial state entropy change.
B. Dacre, D. F. Maundrell and S. E. Rees, J. Chem. Soc., Perkin Trans. 2, 1973, 1060 DOI: 10.1039/P29730001060
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