The hydrolysis of acetylglycine and glycyltyrosine have been carried out over a wide range of acidities in hydrochloric, perchloric, and sulphuric acids at 100·1 °C. Treatment of the rate data by Zucker–Hammett, Bunnett W and W*, and Bunnett–Olsen linear free energy relationship criteria of mechanism indicates that hydrolysis takes place by a simple bimolecular A-2 mechanism.
J. W. Barnett and C. J. O'Connor, J. Chem. Soc., Perkin Trans. 2, 1973, 685 DOI: 10.1039/P29730000685
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