A mechanism for the concerted loss of the dihydrogen cyanide radical (H2CN˙) from heterocyclic species such as the ions of dibenz[b,f]azepine and its 5-carboxamide formed on electron impact is proposed. A mechanism is also proposed for the loss of hydrogen cyanide from the acridine ion.
K. M. Baker and A. Frigerio, J. Chem. Soc., Perkin Trans. 2, 1973, 648 DOI: 10.1039/P29730000648
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