Although acid-catalysed hydrolyses of t-butyl, 1,1-diethylpropyl, and diphenylmethyl β-D-galactopyranosides proceed by partial alkyl–oxygen fission, no products derivable from this process are detectable in the hydrolysis of these substrates catalysed by the wild-type β-galactosidase of Escherichia coli.
M. Maybury and M. L. Sinnott, J. Chem. Soc., Perkin Trans. 2, 1973, 300 DOI: 10.1039/P29730000300
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