Treatment of D-glucosamine with ethyl N-[carbamoyl(cyano)methyl]formimidate (I) gave the title compound (IIa), an analogue of the nucleoside corresponding to AICAR (5-amino-1-β-D-ribofuranosylimidazole-4-carboxamide 5′-phosphate), in which the linkage between sugar and base is not a glycosidic link.
C. G. Beddows and D. V. Wilson, J. Chem. Soc., Perkin Trans. 1, 1973, 2345 DOI: 10.1039/P19730002345
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