Butane-1-thiol and 1,1-dimethylethane-1-thiol added to some non-conjugated [(I)–(VIII)] and conjugated [(IX)–(XI)] olefins under free radical conditions to yield sulphides. The reactivity order was: conjugated diene > vinyl (anti-Markownikoff addition) > internal double bonds. The conjugated dienes yielded mainly 1,2- and 1,4-adducts.
D. W. Grattan, J. M. Locke and S. R. Wallis, J. Chem. Soc., Perkin Trans. 1, 1973, 2264 DOI: 10.1039/P19730002264
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