Issue 0, 1973

Stereochemistry of the ethoxyethynyl carbinol–αβ-unsaturated ester conversion

Abstract

Carbon dioxide in ethanol rearranges the ethoxyethynyl carbinol derivatives of ketones in the 1-tetralone, indan-1-one, and 2,3-dihydrophenanthren-4(1H)-one series to yield predominantly the cis-αβ-unsaturated esters.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1973, 615-623

Stereochemistry of the ethoxyethynyl carbinol–αβ-unsaturated ester conversion

M. H. Tankard and J. S. Whitehurst, J. Chem. Soc., Perkin Trans. 1, 1973, 615 DOI: 10.1039/P19730000615

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