He(I), He(II) and valence region X-ray photoelectron spectra are reported for the Group VIA hexacarbonyls and are assigned on the basis of published molecular orbital calculations. A pronounced increase in intensity of the first photoelectron band is observed on descending the group, and multiplet structure is clearly discernible on this band in the case of W(CO)6.
B. R. Higginson, D. R. Lloyd, P. Burroughs, D. M. Gibson and A. F. Orchard, J. Chem. Soc., Faraday Trans. 2, 1973, 69, 1659 DOI: 10.1039/F29736901659
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