The kinetics of the pyrolysis of NO2 between 1500 and 2300 K involves the dissociation of NO3 in addition to steps proposed at lower and higher temperatures. The rate of NO2+ NO2→ NO + NO3 was found to be somewhat faster than expected by extrapolation from experiments near 600 K.
P. K. Butt and B. P. Levitt, J. Chem. Soc., Faraday Trans. 1, 1973, 69, 1957 DOI: 10.1039/F19736901957
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