From measurements of the heats of aqueous alkaline hydrolysis at 25 °C the following standard enthalpies of formation are derived: ΔHf°[IOF3,cryst.]298=–554·76 ± 2·51 kJ mol–1(– 132·59 ± 0·6 kcal mol–1) and ΔHf°[IO2F, cryst.]298=–246·4 ± 1·2 kj mol–1(– 58·89 ± 0·29 kcal mol–1).
A. Finch, P. N. Gates and M. A. Jenkinson, J. Chem. Soc., Dalton Trans., 1973, 2725 DOI: 10.1039/DT9730002725
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