Issue 23, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

Some benzyne complexes of osmium derived from dimethylphenylphosphine or dimethylphenylarsine

Antony J. Deeming,   Richard E. Kimber  and  Mark Underhill  

Abstract

The complexes [Os3(CO)11(EMe2Ph)] or [Os3(CO)10(EMe2Ph)2](E = P or As) on heating give C6H4-bridged complexes [HOs3(C6H4)(EMe2)(CO)9], [HOs3(C6H4)(PMe2)(PMe2Ph)(CO)8]. [Os3(C6H4)(Eme2)2(CO)7], and [HOs3(Me2PC6H4C6H3)(PMe2)(CO)8]. When E = As, dimeric complexes containing bridging C6H4 are also obtained. Structures and mechanisms of the fluxional behaviour of these complexes are discussed in the light of n.m.r. spectra.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9730002589
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 2589-2595

Permissions

Request permissions

Some benzyne complexes of osmium derived from dimethylphenylphosphine or dimethylphenylarsine

A. J. Deeming, R. E. Kimber and M. Underhill, J. Chem. Soc., Dalton Trans., 1973, 2589 DOI: 10.1039/DT9730002589

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements