Mixed iron–cobalt binuclear complexes. Part I. Identification of mixed complexes derived from trans-[Co(en)2(H2O)(SO3)]+
Abstract
Products from the reactions of the complex trans-[Co(en)2(H2O)(SO3)]+(en = ethylenediamine) with the ions [Fe(CN)6]4–, [Fe(CN)6]3–, [Co(CN)6]3–, and [Fe(CN)5NO]2– in aqueous solution are µ-cyano-complexes which have been characterised by means of their visible and i.r. spectra.
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