Issue 21, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reaction of tetrafluoroethylene with Se8(AsF6)2 and Se8(Sb2F11)2. Preparation of bis(pentafluoroethyl) triselenide and perfluoroethyldiselenylperfluoroacetyl fluoride

C. David Desjardins  and  Jack Passmore  

Abstract

Solid Se8(AsF6)2 reacts with C2F4 at room temperature to form (C2F5)2Sex(x= 2 or 3). Se8(Sb2F11)2 gives similar products on reaction with C2F4 at 100 °C. In SO2 solution Se8(AsF6)2 and C2F4 give mainly (C2F5)2Se2 and C2F5Se2CF2C[O]F; the latter was characterised by its 19F n.m.r. and mass spectrum.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9730002314
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 2314-2317

Permissions

Request permissions

Reaction of tetrafluoroethylene with Se8(AsF6)2 and Se8(Sb2F11)2. Preparation of bis(pentafluoroethyl) triselenide and perfluoroethyldiselenylperfluoroacetyl fluoride

C. D. Desjardins and J. Passmore, J. Chem. Soc., Dalton Trans., 1973, 2314 DOI: 10.1039/DT9730002314

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements