An assignment for the vibrational spectrum of the anion in K[PtCl3(NH3)],H2O is deduced from single-crystal Raman measurements. Evidence from Raman spectra of powder samples of K[PtCl3(ND3)],D2O and of both the protiated and deuteriated anhydrous materials (Cossa's salt) is also discussed.
D. M. Adams and R. E. Christopher, J. Chem. Soc., Dalton Trans., 1973, 2298 DOI: 10.1039/DT9730002298
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