SCHEDULED MAINTENANCE
The preparation and properties of the bis-π-allyl derivatives (C6H5R)Mo(π-C3H5)2 are described. The butadiene cation [C6H6Mo(π-C3H5)C4H6]+ reacts readily with nucleophiles (Nu = CN, OMe, SMe, H) to give the neutral π-allylic derivatives C6H6Mo(π-C3H5)(π-NuCH2C3H4).
M. L. H. Green, L. C. Mitchard and W. E. Silverthorn, J. Chem. Soc., Dalton Trans., 1973, 1952 DOI: 10.1039/DT9730001952
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