Tungsten hexafluoride reacts with trimethylsilyldiethylamine or trimethyl(pentafluorophenoxo)silane at or below ambient temperature with the replacement of F by –NEt2 or –OC6F5 groups. Compounds isolated were monomeric WF2(NEt2)4, polymeric WF4(NEt2)2 and monomeric WF5OC6F5. WF4(OC6F5)2 appears to exist in cis- and trans-forms and undergoes reorganisation to give other members of the series.
A. Majid, D. W. A. Sharp, J. M. Winfield and I. Hanley, J. Chem. Soc., Dalton Trans., 1973, 1876 DOI: 10.1039/DT9730001876
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