Issue 17, 1973

Structure and bonding in sulphatobis(thiourea)tin(II)

Abstract

The crystal structure of the title compound has been determined from X-ray diffractometer data by Patterson and Fourier methods. Crystals are orthorhombic, space group P21212, with Z= 4 in a unit cell of dimensions: a= 16·98, b= 12·86, c= 5·22 Å. The structure was refined by least-squares methods to R 0·083 for 1023 reflections. The tin atoms are in distorted pyramidal sites surrounded by two sulphate oxygen atoms at 2·41 and 2·24 Å and by two thiourea sulphur atoms at 2·62 and 2·86 Å. The thiourea groups are planar but not equivalent and are linked to the sulphate ions by hydrogen bonding.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 1810-1813

Structure and bonding in sulphatobis(thiourea)tin(II)

J. D. Donaldson, D. G. Nicholson, D. C. Puxley and R. A. Howie, J. Chem. Soc., Dalton Trans., 1973, 1810 DOI: 10.1039/DT9730001810

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