Issue 16, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reaction of low-valent metal complexes with fluorocarbons. Part XXVII. Zerovalent nickel, palladium, and platinum, and iridium(I), palladium(II), and platinum(II) complexes with bis(trifluoromethyl)diazomethane

John Clemens,   Michael Green  and  F. Gordon A. Stone  

Abstract

Reaction of [Pt(stilbene)(PPh3)2], [Pt(PEt3)3], [Pd(t-BuNC)2], [Pd(C6H11NC)2], [Ni(t-BuNC)4] and [Ni(PMePh2)4] with (CF3)2CN2 affords the perfluoroacetone azine complexes [[graphic omitted]·N[double bond, length half m-dash]C(CF3)2L2]. The complexes [M(PhCN)2Cl2](M = Pd or Pt) undergo insertion reactions into the M–Cl bond with (CF3)2CN2, whereas, trans-[IrCl(N2)(PPh3)2] gives the adduct, [[graphic omitted](CF3)2(PPh3)2]. Minor products in the reaction of Pt0 complexes with (CF3)2CN2 include [[graphic omitted]F2(PPh3)2] and cis- and trans-[PtF{CH(CF3)2}(PPh3)2].

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Article information

DOI
https://doi.org/10.1039/DT9730001620
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 1620-1625

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Reaction of low-valent metal complexes with fluorocarbons. Part XXVII. Zerovalent nickel, palladium, and platinum, and iridium(I), palladium(II), and platinum(II) complexes with bis(trifluoromethyl)diazomethane

J. Clemens, M. Green and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1973, 1620 DOI: 10.1039/DT9730001620

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