Issue 14, 1973

Vibrational spectra of some octahedral trimethylphosphine complexes of rhodium and iridium

Abstract

Infrared and Raman spectra below 800 cm–1 of complexes trans-[IrX4(PMe3)2], mer- and fac-[MX3(PMe3)3], trans-[MX2(PMe3)4]+(X = Cl or Br; M = Rh or Ir) and the i.r. spectrum of trans-[IrCl4(PMe3)2] are reported and vibrational assignments proposed. Metal–chlorine and metal–phosphorus stretching frequencies are discussed.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 1489-1493

Vibrational spectra of some octahedral trimethylphosphine complexes of rhodium and iridium

P. L. Goggin and J. R. Knight, J. Chem. Soc., Dalton Trans., 1973, 1489 DOI: 10.1039/DT9730001489

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