Issue 13, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

The iridium(I) cation, [Ir(CO)(CH3CN)(PPh3)2]+ and its substitution reactions

Christopher A. Reed  and  Warren R. Roper  

Abstract

Reaction of IrCl (CO)(PPh3)2 with silver perchlorate in various solvents gives [Ir(CO)(solvent)(PPh3)2]ClO4. Crystalline salts have been isolated where solvent = acetonitrile, benzonitrile, and dimethyl sulphoxide. [Ir(CO)(CH3CN)(PPh3)2]+ redily undergoes substitution reactions with carbon monoxide, phosphines, and isocyanides and, the following cations hsve been characterised: [Ir(CO)3(PPh3)2]+, [Ir(CO)(PPh3)3]+, [Ir(CO)(PPh2Me3)]+, [Ir(CO)(PPh2Et)3]+, [Ir(PPh2Me)4]+, [Ir(CO)(Ph2PCH[double bond, length half m-dash]CHPPh2)2]+, [Ir(CO)(p-Tolylisocyanide)(PPh3)2]+ and [Ir(p-tolylisocyanide)3(PPh3)2]+

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9730001365
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 1365-1370

Permissions

Request permissions

The iridium(I) cation, [Ir(CO)(CH3CN)(PPh3)2]+ and its substitution reactions

C. A. Reed and W. R. Roper, J. Chem. Soc., Dalton Trans., 1973, 1365 DOI: 10.1039/DT9730001365

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements