The chemistry of the dehydrohalogenation reactions of boron tri-iodide–aromatic amine adducts is illustrated. The main difference between boron tri-iodide and other boron halides is the more extensive formation of 1,3-diaza-2,4-diboranaphthalene derivatives (from aromatic amine–boron halide adducts) for the iodide systems. The mechanism of orthoboronation is discussed.
J. R. Blackborow and J. C. Lockhart, J. Chem. Soc., Dalton Trans., 1973, 1303 DOI: 10.1039/DT9730001303
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